So, I found this picture and it reminded of Pride from Full Metal Alchemist: Brotherhood. (Which I fucking love) I recently came up with the idea of doing a concept theme of doing the 7 deadly sins based off Brotherhood. This reminded me of Pride, so I thought I should try to do a picture somewhat related to this, using the hands and the eyes based off the character's power/ability. But there is a problem, I suck with photoshop o.o; and I want to learn how to create a picture kind of similar to this picture here.

Any tips to help me?